Product ID:05205 CLEANING SOLUTION S79964MF
MSDS Date:05/08/1995
FSC:6850
NIIN:00F055055
MSDS Number: CGJBB

FISHER SCIENTIFIC CHEMICAL DIV

1 REAGENT LN
FAIR LAWN, NJ 07410-2802
US

Emergency Phone: 201-796-7100/201-796-7523

Info Phone: 201-796-7100/201-796-7523

Cage: 1B464

FISHER SCIENTIFIC CO. CHEMICAL MFG DIV

FAIRLAWN, NJ 07410-2802 US

Telephone: 201-796-7100

Cage: 1B464

CHROMIC ACID (SOLID OR SOLUTION), CRO3, CHROMIUM (VI)

CAS: 1333-82-0

RTECS: GB6650000

Fraction By Weight: 0.5%

OSHA PEL 0.1 MG/CUM (CRO3)

ACGIH TLV: 0.05 MG/CUM (CR)

SULFURIC ACID (CONFIRMED HUMAN CARCINOGEN BY IARC - GROUP

CAS: 7664-93-9

RTECS: WS5600000

Fraction By Weight: 93.87%

OSHA PEL 1 MG/CUM

ACGIH TLV: 1 MG/CUM=IC

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 5.63%

LD50 LC50 Mixture:ORAL LD50(RAT): 2140 MG/KG SULFURIC ACID
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EYES: SEVERE BURNS, IRREVERSIBLE EYE
INJURY. SKIN: BURNS/SENSITIZATION, ALLERGIC REACTION. INGESTION:
SEVERE/PERMANENT DAMAGE TO THE DIGESTIVE TRACT. GI TRACT BURNS.
INHALATION: ASTHMATIC ATTACKS DUE TO ALLERGIC SENSITIZATION &
IRRITATION OF RESPIRATORY TRACT. MAY CAUSE MUCOUS MEMBRANE BURNS.
(SEE SUPP)
Explanation of Carcinogenicity:SEE INGREDIENTS.
Effects of Overexposure:BURNS, IRRITATION, SORE THROAT, COUGHING,
SHORTNESS OF BREATH, DELAYED LUNG EDEMA. PROLONGED/REPEATED
EXPOSURE: NOSEBLEEDS, NASAL CONGESTION, EROSION OF TEETH,
PERFORATION OF THE NASAL SEPTUM, CHEST P AIN, BRONCHITIS,
CONJUNCTIVITIS

First Aid:EYES: IMMEDIATELY FLUSH W/PLENTY OF WATER FOR 15 MINS. SKIN:
IMMEDIATELY FLUSH W/PLENTY OF SOAP & WATER. INGESTION: DON'T INDUCE
VOMITING. IF CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK/WATER.
INHALAT ION: REMOVE TO FRESH AIR IMMEDIATELY. GIVE CPR/OXYGEN IF
NECESSARY. OBTAIN MEDICAL ATTENTION IN ALL CASES. TREAT
SYMPTOMATICALLY/SUPPORTIVELY.

Extinguishing Media:DRY CHEMICAL
Fire Fighting Procedures:USE WATER SPRAY TO COOL FIRE-EXPOSED
CONTAINERS. WEAR APPROPRIATE PROTECTIVE CLOTHING & SCBA. DON'T USE
WATER DIRECTLY ON FIRE.
Unusual Fire/Explosion Hazard:CONTACT W/WATER CAN CAUSE VIOLENT
LIBERATION OF HEAT & SPLATTERING OF THE MATERIAL.

Spill Release Procedures:CLEAN UP IMMEDIATELY. COVER W/SAND, DRY
LIME/SODA ASH & PLACE IN A CLOSED CONTAINER FOR DISPOSAL.

Handling and Storage Precautions:DON'T STORE NEAR COMBUSTIBLE
MATERIALS. KEEP CONTAINER CLOSED WHEN NOT IN USE. STORE IN A COOL,
DRY, WELL-VENTILATED AREA AWAY FROM INCOMPATIBLES.
Other Precautions:DON'T STORE NEAR ALKALINE SUBSTANCES. DON'T GET IN
EYES, ON SKIN/ON CLOTHING. DON'T ALLOW CONTACT W/WATER. DON'T USE
SOLUTION BEYOND STATED SHELF LIFE DUE TO POTENTIAL PRESSURE
INCREASE. AVOID CONTAMI NATION. DON'T RETURN TO OPENED BOTTLE.

Respiratory Protection:USE A NIOSH-APPROVED RESPIRATOR WHEN NECESSARY.
Ventilation:LOCAL EXHAUST TO CONTROL AIRBORNE LEVELS BELOW RECOMMENDED
EXPOSURE LIMITS. USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves:REQUIRED
Eye Protection:EYEGLASSES/CHEMICAL SAFETY GOGGLES
Other Protective Equipment:PROTECTIVE CLOTHING
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. DESTROY CONTAMINATED SHOES. WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
PROLONGED/REPEATED EXPOSURE MAY CAUSE EROSION OF THE TEETH, PERFORATION
OF THE NASAL SEPTUM. SULFURIC ACID: MAY BE HARMFUL TO AQUATIC LIVE
IN VERY LOW CONCENTRATIONS. IT MAY BE DANGEROUS IF IT ENTERS WATER
INTAKES.

Boiling Pt:B.P. Text:554F
Melt/Freeze Pt:M.P/F.P Text:23F
Vapor Pres:0.001
Spec Gravity:1.9
pH:<7
Solubility in Water:COMPLETE
Appearance and Odor:DARK BROWN VISCOUS LIQUID

Stability Indicator/Materials to Avoid:YES
ALKALINE SUBSTANCES, WATER, METALS, COMBUSTIBLE MATERIALS, ORGANIC
MATERIALS, OXIDIZERS, AMINES, BASES
Stability Condition to Avoid:EXCESSIVE HEAT
Hazardous Decomposition Products:OXIDES OF SULFUR

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE &
FEDERAL REGULATIONS. UN1760 CORROSIVE LIQUID.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.